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1 article(s) from Valluru, Krish

Iridium-catalyzed hydroacylation reactions of C1-substituted oxabenzonorbornadienes with salicylaldehyde: an experimental and computational study

Angel Ho,
Austin Pounder,
Krish Valluru,
Leanne D. Chen and
William Tam

Beilstein J. Org. Chem. 2022, 18, 251–261, doi:10.3762/bjoc.18.30

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Scheme 1: Previously reported metal-catalyzed reactions of heterobicyclic alkenes and applications towards th...

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Scheme 2: Iridium-catalyzed hydroacylation of C₁-substituted OBDs 13a–k with salicylaldehyde 14.

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Scheme 3: Competition reaction of different C₁-substituted OBDs.

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Figure 1: Potential energy profile of the PCM solvation model for the hydrometalation/reductive elimination p...

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Figure 2: Potential energy profile of the PCM solvation model for the carbometalation/reductive elimination p...

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Figure 3: Potential energy profile of the PCM solvation model for the endo hydrometalation/reductive eliminat...

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Figure 4: Potential energy profile of the PCM solvation model for the Ir/diene-catalyzed hydroacylation of Me...

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Published 02 Mar 2022

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